Opening The Power Box: The Race To Store In-Vehicle Electricity Lightly
With the economy now dominating the headlines both generally and in the US presidential campaign, it is worth pointing out that the business, science, and policy worlds are still thinking hard about energy.
Aimed at reducing both oil dependency and GHG emissions, both the Obama and McCain teams have plans for clean cars, as the New York Times outlines.
Both candidates are in favor of plug-in hybrid cars, and the Times points out that the key to improving the battery-only range of hybrids is, astonishingly enough, the batteries.
Lithium ion, (Li-Ion) batteries are emerging as the most likely way of producing cars that can store electricity directly, whether in all electric vehicles (often called EVs) or in hybrids (some combination of internal combustion engine and electric motor).

Lithium ion batteries are relatively new, having been proposed in the 1970s, developed in the 80s, and first marketed (by Sony) in 1991. This is not much time to get a robust, effective and cheap product, and though the batteries for automotive applications are now much more stable, there remain significant hurdles. By comparison, lead acid batteries were invented in 1859 - the same year as oil was discovered in America.
As many people will know to their annoyance, some lithium ion batteries in laptops had to be recalled because of the danger of their spontaneously igniting or even exploding. This would not be good in a vehicle occupied by humans. Lithium is a highly reactive element, but when designed with other compounds, such as iron and phosphates, the danger of fires and explosions in batteries is said to be removed.
The biggest difficulties facing large-scale deployment of lithium now appear to be price and battery management systems. Li-Ion batteries are more difficult to make than other rechargeable batteries and are, as yet, made in far smaller quantities than other kinds of rechargeable battery. There is considerable effort being made to further improve battery chemistry and stability, to scale up battery production, and to reduce the price.
Battery management systems are critical to the performance and safety of Li-Ion batteries. Li-ion batteries are rather delicate creatures and must be treated like thoroughbred horses. Specifically, they should not ever be discharged below about 2.5 volts per cell, nor charged at much above 4 volts. The former process can ruin the battery, while the latter can lead to thermal instability, to put it nicely.
Li-ion batteries for vehicles are sufficiently young that as yet, there are not many well tried battery management systems available, and even fewer that are sufficiently open in design that they can easily interface with chargers upstream and electric motor controllers downstream.
There is a further opportunity-problem and that is that li-ion batteries do not normally like to be fast charged. Yet, in order to make electric vehicles maximally efficient, it is necessary to recapture downhill and braking energy as electrical regeneration.
Regeneration can result in very large amounts of power going into the batteries - just what Li-Ion batteries don't like. However, there is an opportunity here: electrochemical capacitors (sometimes called ultra-capacitors) are very pleased to receive extremely large currents (as long as they are designed for it). Furthermore, ultra-capacitors can be cycled millions of times without detriment (just like the small capacitors in a radio).
The obvious thing to do is to combine li-ion batteries with ultra-capacitors - the vehicles would be more efficient and the life of the Li-ion battery could be greatly extended. The main problems are the added initial cost and yet more battery management issues.
However, the technical problems are definitely soluble, especially if we have more open battery and renewable power management systems. Such systems would ideally be part of a much larger movement towards open power control systems, designed to take any kind of renewable energy and apply it to any kind of load, be it storage, immediate use, or storage followed by use.
The electronics to do this are in principle here now, but the protocols and platforms are not. This could be an interesting area for those interested in how to be part of the great new game of renewables without having to bet their shirt on a particular renewable energy generation technology.
Cheap and well controlled li-ion batteries in partnership with ultra-capacitors and renewable electricity can and will make a huge impact on our many transport dilemmas. Will we find the money and will to get there fast enough?









From my perspective, this is the kind of proposal that gets lumped into what I have taken to calling "TechnoFantasy". We do not possess a robust electrical grid. The financial crisis will create conditions that lead to it becoming yet more brittle. To assume we will be able to continue our happy motoring ways with EV's requires, from my perspective, a significant stretch of the imagination. Like it or not, we face a low energy future. Our demonstration site, found at http://entropypawsed.org, seeks to promote nature linked low energy lifestyles that are elegant and graceful.
What about compressed air as a battery? I should think CA batteries deserve mention in an article like this since they have distinct advantages over other batteries:
1) they don't require exotic materials
2) MDI is poised to commercialize them
3) they are cheaper and support more cycles than other batteries
Change your lifestyle somewhat, and you don't have to wait for better batteries. Lead acid can work fine in small, light vehicles. I drove my electric scooter to work again today.
It's an amazing vehicle. I commute to work for about 4 cents of electricity per day and have a range of 60 miles.
Since I got it, I rarely use my SUV and have only used $8 of gas in the past three months.
Flywheels have better specific energy and specific power than current capacitors, so would be a better choice for adsorbing braking energy. See
http://en.wikipedia.org/wiki/Energy_density and
http://www.engineering.sdsu.edu/~hev/energy.html.
How is lithium mined? What's the energy outlay? and the environmental impact? Are we doing with energy what we do with food? Cheap,monoculture,invisible. But the impact on the whole is devastating. Local solutions, anyone? Lifestyle changes?
Simply put, dragging around 2 tons to commute to work is totaly ridiculous and squanders energy at an unbelievable rate. The unconsidered (by this article) answer is 300-400 pound vehicles that can have batteries augmented by solar pv's, peddling, and small fuel cells. The same platfform is amenable to personal computer presence and all the good that goes with that - think about it!
http://ww4report.com/node/6296
Chile is already mining Lithium.... but Bolivians are keen to keep control...the foreigners took the gold, silver, coca.... but they stopped the rank exploitation of gas... now its lithium, with even higher stacks!
cheers
Paul Bruce
Sorry that there aren't many portals into truly current research sites...am working on that..But storage is no longer an issue, except by those who have been leap-frogged and need to reinvent the wheel for themselves...Take a look at the "Zhang group" site at vt.edu..20 times the energy density of lithium and the reaction , going from G1P to G6P, is spontaneous/on- demand, and happens at ambient T&P...enjoy, TD
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